Detection of ethanol, acetone, and propanal in TMC-1 New O-bearing complex organics in cold sources

We present the detection of ethanol (C2H5OH), acetone (CH3COCH3), and propanal (C2H5CHO) toward cyanopolyyne peak TMC-1. These three O-bearing complex organic molecules are known to be in warm interstellar clouds, but had never been observed a starless core. The addition these new pieces puzzle cold clouds stresses rich chemical diversity dense cores stages prior onset star formation. detections ethanol, acetone, were made framework QUIJOTE, deep line survey TMC-1 Q band that is being carried out with Yebes 40m telescope. derive column densities (1.1 +/- 0.3)e12 cm-2 for C2H5OH, (1.4 0.6)e11 CH3COCH3, (1.9 0.7)e11 C2H5CHO. formation investigated aid detailed model which includes gas ice chemistry. calculated abundances at time around 2e5 yr reasonable agreement values derived from observations. mechanisms our as follows. Ethanol formed on grains by atomic carbon methanol followed hydrogenation non-thermal desorption. Acetone produced gas-phase reaction between oxygen two different isomers C3H7 radical, where latter follows C3 A route involving (CH3)2COH+ through several ion-neutral reactions its dissociative recombination electrons do also contribute acetone.